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Published on October 20th, 2017 | By: Faye Oney

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New definition of glass describes non-equilibrium state of matter ending in crystallization

Published on October 20th, 2017 | By: Faye Oney

[Image above] Credit: Vitrix Hot Glass; YouTube

 

 

Glass is a material that seems to have a split personality. Is it a solid? Is it a liquid? Could it be both?

 

A simple Google search brings up dozens of articles on the topic. And if you peruse the results, you encounter a variety of opinions on the subject.

 

Unlike liquids, atoms in most solid materials are arranged in an orderly crystalline structure. Atoms in liquids can’t seem to sit still—they’re constantly moving, like young children after a large dose of sugar. Glass’s atoms are not arranged like other neat and tidy solids.

 

That’s why glass is a non-crystalline material—one that is not organized in a distinct pattern or shape. The glass transition from liquid to solid happens so fast that the atoms and molecules don’t have time to get their act together and line up in an orderly fashion.

 

What happens to glass over a long period of time? Researchers have already debunked the flowing glass window myth earlier this year by proving that the glass in medieval windows only succumbs to gravity after very long geological time scales.

 

So who better to weigh in on the glass solid–liquid debate than people who study glass for a living?

 

Researchers Edgar Zanotto, professor in the Department of Materials Engineering at the Federal University of São Carlos, and John Mauro, professor of materials science and engineering at Penn State University, have authored a new definition of glass, recently published in the Journal of Non-Crystalline Solids.

 

“There are several definitions of glass, but most of them contain serious errors,” Zanotto explains in a news release on Agência FAPESP. “Many definitions say glass is a solid, and others say it’s an isotropic material [whose properties are the same in all directions], but many glasses are not.”

 

“Glass is neither a true solid nor a true liquid, but rather a unique hybrid phase that combines both solid-like and liquid-like qualities,” Mauro states in an email.

 

Credit: Amazing Compilations; YouTube

 

The duo proposed two improved definitions of glass—one for the layman, and an advanced, more detailed version for glass scientists and researchers who understand glass transition.

 

Glass is a non-equilibrium, non-crystalline state of matter that appears solid on a short time scale but continuously relaxes towards the liquid state.

 

Glass is a non-equilibrium, non-crystalline condensed state of matter that exhibits a glass transition. The structure of glasses is similar to that of their parent supercooled liquids (SCL), and they spontaneously relax toward the SCL state. Their ultimate fate, in the limit of infinite time, is to crystallize.

 

Their research was based on three different characteristics of glass, which distinguish it from solids, that were present in previously published articles, according to Zanotto:

 

  • The structure of glass is very similar to that of the liquids from which it is formed;
  • Glass flows (deforms) spontaneously over time and in response to minimal pressure, which can be less than the action of gravity; and
  • At the end of its existence, glass eventually crystallizes.

 

Mauro, formerly of Corning Incorporated and an ACerS Fellow, spent years at the company as a glass researcher—and was one of the co-inventors of the company’s signature product, Gorilla Glass. Zanotto, also an ACerS Fellow, heads the São Carlos Center of Research, Technology and Education in Vitreous Materials (CeRTEV), a lab that conducts state-of-the-art research on glass and ceramics.

 

“We hope that our new definition of glass will help inspire students to learn more about this fascinating material,” Mauro says.

 

The paper, published in the Journal of Non-Crystalline Solids, is “The glassy state of matter: Its definition and ultimate fate” (DOI: 10.1016/j.jnoncrysol.2017.05.019).

 

 

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One Response to New definition of glass describes non-equilibrium state of matter ending in crystallization

  1. Thomas O'Holleran says:

    An interesting concept. It would be helpful to attach at least an approximate temporal reference to this concept. “Equilibrium” is notoriously difficult to study (especially for amorphous materials), but some way to unambiguously accelerate the approach to equilibrium would be a real leap forward (Thesis topic, anyone?). Thermal “stimuli” have been studied for quite some time, but results can be difficult to interpret in terms of approach to equilibrium. What about pressure as a way to “grease the wheels” of approach to equilibrium? How about other “lubricants” such as water that might be useful for silica-based glasses in hydrothermal studies, although corrosion products might complicate things? How about alternating electric fields that couple with network modifiers or other components of glasses? What about magnetic fields? Another way to think about it is if a glass is sitting on top of an energy “hill,” what would it take to nudge it downhill a little way? Anyone?

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